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Identify the dominant (strongest)type of intermolecular force present in Cl2(l).

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Octane is a liquid component of gasoline. Given the following vapor pressures of octane at various temperatures, estimate the boiling point of octane in Leadville, Colorado, where the atmospheric pressure is 496 mmHg. 400 mmHg @ 104°C, 500 mmHg @ 111°C, 600 mmHg @ 117°C, 700 mmHg @ 122°C, 760 mmHg @ 125°C


A) 125°C
B) 120°C
C) 115°C
D) 110°C
E) 105°C

F) A) and B)
G) A) and C)

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Given the following compound and its boiling point, identify whether it is polar or nonpolar: F2, -188.1°C.

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Which is expected to have a higher boiling point, C8H18 or C4H10?

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Boron nitride, BN3, melts at approximately at 3,000°C under high pressure.This materal is almost as hard as diamond.What kind of crystal is this?

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Krypton has a higher melting point than argon because of its


A) hydrogen bonding.
B) stronger dispersion forces.
C) permanent dipole moment.
D) ionic bonds.
E) greater ionization energy.

F) B) and E)
G) B) and D)

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Identify the dominant (strongest)type of intermolecular force present in H2S(g).

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What phase exists at the point labeled c? What phase exists at the point labeled c?

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Indicate all the types of intermolecular forces of attraction in CHCl3(l).

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Which of the following properties indicates the presence of strong intermolecular forces in a liquid?


A) a low heat of vaporization
B) a low critical temperature
C) a low vapor pressure
D) a low boiling point
E) None of the above.

F) None of the above
G) A) and E)

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Calculate the amount of heat needed to melt 2.00 kg of iron at its melting point (1,809 K) , given that Δ\Delta Hfus = 13.80 kJ/mol.


A) 494 kJ
B) 27,600 kJ
C) 27.6 kJ
D) 27,600 J
E) 25,000 kJ

F) B) and C)
G) C) and D)

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Indicate all the types of intermolecular forces of attraction in SF6(g).

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A liquid boils when its


A) vapor pressure is exactly 1 atmosphere.
B) vapor pressure is equal to, or greater than, the external pressure pushing on it.
C) temperature is equal to 273 K (standard temperature) .
D) temperature is greater than room temperature.

E) A) and C)
F) A) and D)

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Which of the following would be expected to have the lowest vapor pressure at room temperature?


A) ethanol, bp = 78°C
B) methanol, bp = 65°C
C) water, bp = 100°C
D) acetone, bp = 56°C

E) A) and C)
F) None of the above

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For which of the following species are the dispersion forces strongest?


A) C4H10
B) C5H12
C) C6H14
D) C7H16
E) C8H18

F) A) and B)
G) A) and E)

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Which one of the following substances crystallizes as a molecular solid?


A) KI
B) SiO2
C) Sn
D) CH3OH
E) Al2(SO4) 3

F) B) and D)
G) B) and E)

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Find the temperature at which ethanol boils on a day in the mountains when the barometric pressure is 547 mmHg.(Given: The heat of vaporization of ethanol is 39.3 kJ/mol; the normal boiling point of ethanol is 78.3°C.)


A) 76.5°C
B) 69.9°C
C) 10.0°C
D) 77.9°C
E) 74.6°C

F) None of the above
G) B) and C)

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The atomic planes in a graphite crystal are separated by 335 pm. At what angle would you find the first-order (n = 1) diffraction of 0.154 nm X-rays from a graphite crystal?


A) 27.4°
B) 66.8°
C) 0.232°
D) 13.3°
E) 2.63°

F) A) and E)
G) A) and D)

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Which one of the following substances is expected to have the highest boiling point?


A) Br2
B) Cl2
C) F2
D) I2

E) A) and B)
F) None of the above

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Indicate all the types of intermolecular forces of attraction in HCl(g).

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