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Picric acid has been used in the leather industry and in etching copper. However, its laboratory use has been restricted because it dehydrates on standing and can become shock sensitive. It has an acid dissociation constant of 0.42. What is the [H3O+] for a 0.20 M solution of picric acid?


A) 0.022 M
B) 0.052 M
C) 0.15 M
D) 0.20 M
E) 0.29 M

F) B) and C)
G) C) and D)

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What is the name of a proton acceptor in an acid-base reaction?


A) Arrhenius acid
B) Arrhenius base
C) Brønsted acid
D) Brønsted base
E) Lewis base

F) C) and D)
G) C) and E)

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In aqueous solutions at 25°C, the sum of the hydroxide ion and hydronium ion concentrations ([H3O+] + [OH -]) equals 1 × 10-14.

A) True
B) False

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Which statement is true regarding the reversible reaction below? H2CO3+ F- Which statement is true regarding the reversible reaction below? H<sub>2</sub>CO<sub>3</sub>+ F<sup>- </sup> <sup> </sup>   HCO<sub>3</sub>+ HF. K<sub>a1</sub>(H<sub>2</sub>CO<sub>3</sub>)  = 4.2 × 10<sup>-7</sup>; K<sub>a</sub>(HF)  = 7.1 × 10<sup>-4</sup> A)  At equilibrium, [HF] > [H<sub>2</sub>CO<sub>3</sub>] because HF is a stronger acid than H<sub>2</sub>CO<sub>3</sub>. B)  At equilibrium, [HF] > [H<sub>2</sub>CO<sub>3</sub>] because H<sub>2</sub>CO<sub>3</sub> is a stronger acid than HF. C)  At equilibrium, [HF] = [H<sub>2</sub>CO<sub>3</sub>]. D)  At equilibrium, [H<sub>2</sub>CO<sub>3</sub>] > [HF] because HF is a stronger acid than H<sub>2</sub>CO<sub>3</sub>. E)  At equilibrium, [H<sub>2</sub>CO<sub>3</sub>] > [HF] because H<sub>2</sub>CO<sub>3</sub> is a stronger acid than HF. HCO3+ HF. Ka1(H2CO3) = 4.2 × 10-7; Ka(HF) = 7.1 × 10-4


A) At equilibrium, [HF] > [H2CO3] because HF is a stronger acid than H2CO3.
B) At equilibrium, [HF] > [H2CO3] because H2CO3 is a stronger acid than HF.
C) At equilibrium, [HF] = [H2CO3].
D) At equilibrium, [H2CO3] > [HF] because HF is a stronger acid than H2CO3.
E) At equilibrium, [H2CO3] > [HF] because H2CO3 is a stronger acid than HF.

F) A) and D)
G) A) and C)

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Which one of these salts will form an acidic solution upon dissolving in water?


A) LiBr
B) NaF
C) NH4Br
D) KOH
E) NaCN

F) A) and E)
G) A) and D)

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What is the conjugate base of HSO4- in the reaction below? CO32- + HSO4- What is the conjugate base of HSO<sub>4</sub><sup>-</sup> in the reaction below? CO<sub>3</sub><sup>2-</sup> + HSO<sub>4</sub><sup>-</sup>   HCO<sub>3</sub><sup>-</sup> + SO<sub>4</sub><sup>2-</sup> A)  HSO<sub>4</sub><sup>-</sup> B)  CO<sub>3</sub><sup>2-</sup> C)  OH<sup>-</sup> D)  H<sub>3</sub>O<sup>+</sup> E)  SO<sub>4</sub><sup>2-</sup> HCO3- + SO42-


A) HSO4-
B) CO32-
C) OH-
D) H3O+
E) SO42-

F) B) and E)
G) None of the above

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What is the value of Kb for the formate anion, HCOO- ? Ka (HCOOH) = 2.1 × 10-4


A) -2.1 × 10-4
B) 2.1 × 10-4
C) 6.9 × 10-6
D) 4.8 × 10-11
E) 2.1 × 10-18

F) A) and B)
G) B) and E)

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The substance NH3 is considered to be


A) a weak acid.
B) a weak base.
C) a strong acid.
D) a strong base.
E) a neutral compound.

F) A) and C)
G) C) and D)

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What is the concentration of OH- in a 0.083 M NaOH solution?


A) 0.083 M
B) 1.21 × 10-13 M
C) 8.30 × 10-16 M
D) 7 M
E) 8.30 × 1012 M

F) A) and E)
G) All of the above

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Which is the weakest acid?


A) SO42-
B) H2SO3
C) H2SO4
D) HSO4-
E) HSO3-

F) None of the above
G) B) and E)

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A student adds 0.1 mol of oxalic acid and 0.1 mol of sodium dihydrogen phosphate to enough water to make 1.0 L of solution. The following equilibrium is established with the concentrations of the products greater than the concentrations of the reactants. Which of the statements about the equilibrium system is correct? H2C2O4(aq) + H2PO4-(aq) A student adds 0.1 mol of oxalic acid and 0.1 mol of sodium dihydrogen phosphate to enough water to make 1.0 L of solution. The following equilibrium is established with the concentrations of the products greater than the concentrations of the reactants. Which of the statements about the equilibrium system is correct? H<sub>2</sub>C<sub>2</sub>O<sub>4</sub>(aq)  + H<sub>2</sub>PO<sub>4</sub><sup>-</sup>(aq)    HC<sub>2</sub>O<sub>4</sub><sup>-</sup>(aq)  + H<sub>3</sub>PO<sub>4</sub>(aq)  A)  Oxalic acid is a weaker acid than phosphoric acid. B)  The hydrogen oxalate anion, HC<sub>2</sub>O<sub>4</sub><sup>-</sup>, is a stronger base than the dihydrogen phosphate anion, H<sub>2</sub>PO<sub>4</sub><sup>-</sup>. C)  Phosphoric acid is a weaker acid than oxalic acid. D)  The dihydrogen phosphate anion, H<sub>2</sub>PO<sub>4</sub><sup>-</sup>, is a stronger acid than oxalic acid. E)  Water is a stronger acid than either oxalic or phosphoric acids. HC2O4-(aq) + H3PO4(aq)


A) Oxalic acid is a weaker acid than phosphoric acid.
B) The hydrogen oxalate anion, HC2O4-, is a stronger base than the dihydrogen phosphate anion, H2PO4-.
C) Phosphoric acid is a weaker acid than oxalic acid.
D) The dihydrogen phosphate anion, H2PO4-, is a stronger acid than oxalic acid.
E) Water is a stronger acid than either oxalic or phosphoric acids.

F) B) and E)
G) A) and C)

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A solution of sodium acetate (CH3COONa) in water is weakly basic.

A) True
B) False

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Acid strength increases in the series HCN < HF < HSO4-. Which of these species is the strongest base?


A) H2SO4
B) SO42-
C) F-
D) CN -
E) HSO4-

F) A) and E)
G) B) and D)

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What is the conjugate acid of HS-?


A) HS2
B) S2-
C) HS
D) H2S
E) SOH

F) None of the above
G) B) and C)

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RCOOH is an organic compound which is in the ________ family.

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Which is a Lewis acid?


A) NH3
B) NH4+
C) H2O
D) BF3
E) F-

F) A) and E)
G) B) and C)

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NH3 is a typical Lewis base.

A) True
B) False

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What is [OH-] for a solution at 25°C that has [H3O+] = 8.23 × 10-2 M?


A) 8.23 × 10-2 M
B) 1.22 × 10-6 M
C) 8.23 × 10-12 M
D) 1.22 × 10-13 M
E) 8.23 × 10-16 M

F) A) and E)
G) A) and D)

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When the cation of a salt is the conjugate acid of a weak base then a solution of this salt will be ________.

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Since arsenic is a nonmetal, As2O3 is expected to be a/an ________ oxide.


A) acidic
B) ionic
C) amphoteric
D) neutral
E) basic

F) B) and E)
G) C) and E)

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